Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 10, Pages 3474-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9007276
Keywords
-
Categories
Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [18064016, 8GS0207A]
- Grants-in-Aid for Scientific Research [18GS0207, 18064016] Funding Source: KAKEN
Ask authors/readers for more resources
A ditantalum hydride complex undergoes head-to-head C-C coupling of six CO molecules under mild conditions to produce an octaanionic C6O6 unit. During the reaction, eight-electron reduction of six CO molecules takes place. In the product, the C6O6 unit is coordinated to four tantalum metals through six oxygen and two carbon atoms. The geometrical parameters within the Ta4C6O6 core indicate significant contribution from a hexatriene-hexaolate form.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available