4.8 Article

Complete Conversion of Hydrous Hydrazine to Hydrogen at Room Temperature for Chemical Hydrogen Storage

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 50, Pages 18032-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja908037t

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Funding

  1. JSPS
  2. AIST

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A synergic effect of Rh and Ni in the bimetallic Rh4Ni nanocatalyst (Rh/Ni ratio = 4:1) makes it possible to achieve a 100% selectivity for hydrogen generation by complete decomposition of hydrous hydrazine at room temperature. The Rh,Ni nanocatalysts with a particle size of similar to 3 nm were prepared by alloying Rh and Ni using a coreduction process in the presence of hexadecyltrimethyl ammonium bromide (CTAB).

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