4.8 Article

Insertion Polymerization of Acrylate

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 2, Pages 422-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja808017n

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Funding

  1. BMBF [03X5505]
  2. DFG [1388/4]

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Multiple insertions of acrylate in copolymerization with ethylene, and an insertion homooligomerization of methyl acrylate were observed for the first time. Key to these findings, and to mechanistic insights reported, are labile-substituted complexes as catalyst precursors.

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