Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 12, Pages 4200-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja900328x
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Funding
- Japan Society for the Promotion of Science (JSPS)
- Grants-in-Aid for Scientific Research [21225002] Funding Source: KAKEN
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Palladium-catalyzed allylic amination using aqueous ammonia for the preparation of primary amines has been realized. It is noteworthy that the use of aqueous ammonia is essential and that ammonia gas did not react at all. The first catalytic asymmetric synthesis using aqueous ammonia as a nitrogen source has also been demonstrated.
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