4.8 Article

Pentacoordinate Organoantimony Compounds That Isomerize by Turnstile Rotation

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 10, Pages 3418-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja808113q

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan [18064013]
  2. Grants-in-Aid for Scientific Research [18064013] Funding Source: KAKEN

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Two stereoisomers of pentacoordinate antimony compounds (stiboranes) with a new rigid tridentate ligand were synthesized, and the isomerization was found to proceed by the turnstile rotation (TR) mechanism with the tridentate Ligand as a trio and the two monodentate ligands as a pair.

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