Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 44, Pages 15974-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja905264a
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Funding
- ICIQ foundation
- Consolider Ingenio [CSD2006-0003]
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A novel protocol for the direct carbon dioxide insertion (CO2) into aryl. halides in a catalytic manner is presented herein. Unlike other carboxylation methods using CO2, there is no need for the synthesis of the corresponding organometallic intermediates. Additionally, and in contrast to the well.-established carbonylation processes, our protocol does not use highly toxic CO for the preparation of benzoic acids. Furthermore, this method is distinguished by its mild conditions, allowing the tolerance of a wide range of functional groups and substitution patterns. The crucial step of the process involves a challenging catalytic CO2 insertion into Pd-C bonds.
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