4.8 Article

Highly Active and Robust Cp* Iridium Complexes for Catalytic Water Oxidation

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 25, Pages 8730-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja901270f

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Funding

  1. NSF [CHE-0614403]
  2. NIH [GM32715]

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A series of Cp*Ir catalysts are the most active known by over an order of magnitude for water oxidation with Ce(IV). DFT calculations support a Cp*Ir=O complex as an active species.

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