Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 34, Pages 12078-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja906040t
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- EPFL
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Ni-catalyzed Sonogashira coupling of nonactivated, B-H-containing alkyl halides, including chlorides, is reported. The coupling is tolerant to a wide range of functional groups, including ether, ester, amide, nitrite, keto, heterocycle, acetal, and aryl halide, in both coupling partners. The coupling can be selective for a specific C-X bond (X = 1, Br, Cl) and allows for orthogonal functionalization of alkyl halides with multiple reactive sites.
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