Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 21, Pages 7206-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja810050y
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Funding
- National Science Foundation [CHE-0616759, DMR-0805259]
- DOE [DE-FG02-07ER46467]
- Ford Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [805259] Funding Source: National Science Foundation
- U.S. Department of Energy (DOE) [DE-FG02-07ER46467] Funding Source: U.S. Department of Energy (DOE)
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The synthesis and characterization of two new thiophene copolymers with backbone phthalimide units is reported. Thin-film optical and wide-angle X-ray diffraction measurements indicate extended electronic conjugation and close intermolecular pi-stacking for both polymers. Ambient carrier mobility of thin-film transistors prepared from these polymers is as high as 0.28 cm(2)/(V s) with an on/off ratio greater than 10(5).
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