Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 27, Pages 9486-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9030566
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Funding
- National Natural Science Foundation of China [20825104, 20731006, 20821061]
- NSF of Fujian Province [E0420003]
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By combination of Nb5+ (having a d(0) electronic configuration) and the tone-pair-containing iodate anion, a new SHG material, BaNbO(IO3)(5), has been prepared. It exhibits a very large SHG response (similar to 14 times that of KH2PO4 and similar to 660 times that of alpha-SiO2) and is phase-matchable, The material has high thermal stability and a wide transparent region.
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