Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 40, Pages 14218-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9065267
Keywords
-
Categories
Funding
- Specially Promoted Research [18002011]
- MEXT (Japan)
- JSPS Research Fellowship for Young Scientists
Ask authors/readers for more resources
Iridium(III)-salen complexes were found to efficiently catalyze the enantioselective C-H carbene insertion. The insertion reaction at the a-position of tetrahydrofuran or at the methylene of 1,4-cyclohexadiene proceeded with high enantio- (up to 99%) and diastereoselectivity (up to >20:1 dr; in the former reaction) by using an appropriate combination of complex (1, 2, or 3) and alpha-diazoacetate (alpha-aryt-alpha-diazoacetates or alpha-diazopropionate) as the carbene source.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
