Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 22, Pages 7562-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9031049
Keywords
-
Categories
Funding
- Deutsche Forschungsgemeinschaft
- Fonds der Chemischen Industrie
Ask authors/readers for more resources
The unique isotable silanone complex 3 has been synthesized and isolated in 94% yield by the remarkably facile oxygenation of the NHC-silylene precursor 2 featuring a Si(II) atom with unusually high nucleophilicity. The latter precursor is easily accessible by reaction of the stable silylene 1 with the corresponding N-heterocyclic carbene (NHC) at -60 degrees C. The remarkably short Si=O distance of 1.541(2) angstrom in 3 suggests the presence of a betaine-like Si=O pi system with balanced electrostatics.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
