Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 18, Pages 6350-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9015827
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Funding
- NSF [CHE-0555425]
- NIH [GM-080422]
- NCBC [2008-IDG-1010]
- Duke University NMR
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0911265] Funding Source: National Science Foundation
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Treatment of a suspension of (IPr)AuCl [IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidine] and AgSbF6 (1:1) with isobutylene at room temperature for 12 h led to isolation of [(NHC)Au(eta(2)-H2C=CMe2)](+) SbF6- (1a) in 98% yield, which was characterized by spectroscopy and X-ray crystallography. A number of cationic gold pi-alkene complexes were isolated employing a procedure similar to that used to isolate 1a, two of which were analyzed by X-ray crystallography. Spectroscopy, Xray crystallography, and alkene binding studies were in accord with a gold-(pi-alkene) interaction dominated by a-donation from the alkene to gold.
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