Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 45, Pages 16380-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9061097
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Funding
- National Natural Science Foundation of China [90606005]
- Jiangsu Province Foundation of Natural Science [BK2006717]
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Fullerene can activate molecular hydrogen and is a novel nonmetal hydrogenation catalyst. The hydrogenation of aromatic nitro compounds to amino aromatics is achieved on this catalyst with high conversion and selectivity under 1 atmospheric pressure of H, and light irradiation at room temperature or under conditions of 120-160 degrees C and 4-5 MPa H-2 pressure without tight irradiation, which is comparable to the case with a noble metal catalyst.
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