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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 47, Pages 17099-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9043906
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We demonstrate a photochemical reaction between graphene and benzoyl, peroxide. This reaction introduces spatially localized defects into the graphene basal plane. The reactivity of the single-layer graphene is similar to 14 times higher than that of the double-layer graphene. Our result suggests that photoexcited graphene transfers a hot electron to benzoyl peroxide and induces its decomposition to a phenyl radical.
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