Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 46, Pages 16675-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja907742z
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Funding
- University of California, San Diego
- National Science Foundation [CHE-0546531, CHE-9709183, CHE-0116662, CHE-0741968]
- Department of Energy [DE-FG0208ER46519]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0741968] Funding Source: National Science Foundation
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Postsynthetic covalent modification of a metal-organic framework (MOF) is shown to activate breathing behavior upon adsorption of certain gases. The findings reported suggest that chemical modification can be used to trigger, tune, and control the flexibility of MOFs in an unprecedented fashion. By manipulation of MOF breathing and flexibility, the development of new MOFs with selective gas adsorption properties may be realized.
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