4.8 Article

Topochemical Limits for Solid-State Photoreactivity by Fine Tuning of the π-π Interactions

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 21, Pages 7247-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja902094b

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Funding

  1. MEXT of the Japanese Government

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The limiting topochemical criteria for photodimerization were studied by modulation of the TT-TT stacking interactions between self-templating planar molecules with hydrogen bonding. The product yield and composition can be controlled predominantly by the distance between the reactive bonds.

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