Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 36, Pages 12882-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja904749x
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Funding
- JSPS [20245021]
- Naito Foundation
- Grants-in-Aid for Scientific Research [20245021] Funding Source: KAKEN
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A highly enantioselective anti-diastereoselective hetero-Diets-Alder reaction between a glyoxylate and siloxy- or methoxydienes using a chiral phosphoric acid catalyst that possesses less bulky phenyl groups at the 3 and 3' positions of binaphthyl has been developed. The diastereoselectivities presented are disparate to those previously reported for hetero-Diets-Alder reactions catalyzed by a chiral Lewis acid.
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