4.8 Article

Chemical Modification of Epitaxial Graphene: Spontaneous Grafting of Aryl Groups

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 4, Pages 1336-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja8057327

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Funding

  1. DOD/DMEA [H94003-07-2-0703]
  2. NSF-MRSEC [DMR-0820382]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Materials Research [820382] Funding Source: National Science Foundation

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The addition of nitrophenyl groups to the surface of few-layer epitaxial graphene (EG) by the formation of covalent carbon-carbon bonds changed the electronic structure and transport properties of the EG from near-metallic to semiconducting.

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