Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 43, Pages 15588-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja906735v
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Funding
- National Natural Science Fund for Distinguished Young Scholars of China [20725101]
- NNSF of China [50872133]
- NSF of Fujian Province [E0510030]
- 973 Program [2006CB932904]
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Through the use of bis(carboxyethylgermanium) sesquioxide as the germanium source, lanthanide has been successfully introduced into germanate systems under hydrothermal conditions, resulting in a novel lanthanide germanate cluster organic framework with twofold-interpenetrating nets built from Nd8Ge12 cluster units. To avoid the interpenetration, a second ligand, 2-picolinic acid, was introduced into the above system, resulting in the formation of a series of noninterpenetrating networks constructed from Ln(11)Ge(12) cluster units, as expected.
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