Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 48, Pages 17597-17604Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9057053
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Funding
- Global COE Program
- MEXT, Japan [19350099, 21655074]
- JST (PRESTO)
- Grants-in-Aid for Scientific Research [19350099, 21655074] Funding Source: KAKEN
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We report a new type of ordered monolayer for the surface modification of organic semiconductors. Fullerene derivatives with fluorocarbon chains ([6,6]-phenyl-C-61-buryric acid 1H,1H-perfluoro-1-alkyl ester or FCn) spontaneously segregated as a monolayer on the surface of a [6,6]-phenyl-C-61-butyric acid methyl ester (PCBM) film during a spin-coating process from the mixture solutions, as confirmed by X-ray photoelectron spectroscopy (XPS). Ultraviolet photoelectron spectroscopy (UPS) showed the shift of ionization potentials (IPs) depending on the fluorocarbon chain length, indicating the formation of surface dipole moments. Surface-sensitive vibrational spectroscopy, sum frequency generation (SFG) revealed the ordered molecular orientations of the C-60 Moiety in the surface FCn layers. The intensity of the SFG signals from Fc(n) on the surface showed a clear odd-even effect when the length of the fluorocarbon chain was changed. This new concept of the surface-segregated monolayer provides a facile and versatile approach to modifying the surface of organic semiconductors and is applicable to various organic optoelectronic devices.
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