Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 40, Pages 14234-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja906646v
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- Natural Sciences and Engineering Research Council (NSERC) of Canada
- Dalhousie University
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Ir silyl pincer complexes insert into the N-H bonds of anilines and ammonia under mild conditions to form isotable [Cy-PSiP]Ir(H)(NHR) complexes that are resistant to N-H bond reductive elimination at room temperature, even in the presence of arenes, alkenes, and phosphines.
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