4.8 Article

Terminal Alkyne Activation by Frustrated and Classical Lewis Acid/Phosphine Pairs

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 24, Pages 8396-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja903650w

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Funding

  1. NSERC of Canada
  2. Canada Research Chair

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Frustrated and classical Lewis pairs arising from combinations of Lewis acids and phosphines react with terminal alkynes either via C-H activation forming an alkynylborate salt or by addition to alkyne giving a zwitterionic phosphonium borate.

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