4.8 Article

Copolymerization of Vinyl Acetate with Ethylene by Palladium/Alkylphosphine-Sulfonate Catalysts

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 41, Pages 14606-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja9050839

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Funding

  1. Grant-in-Aid for Scientific Research on Priority Areas Advanced Molecular Transformations of Carbon Resources
  2. MEXT, Japan
  3. JSPS

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Coordination copolymenzation of vinyl acetate (VAc) with ethylene, leading to linear copolymers that possess in-chain -CH2CH(OAc)- units, has been accomplished using novel palladium complexes bearing alkylphosphine-sulfonate ligands.

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