4.8 Article

Surface-Mediated Visible-Light Photo-oxidation on Pure TiO2(001)

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 41, Pages 14670-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja9066805

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We used STM to observe visible tight photo-oxidation reactions of formic acid on the ordered lattice-work structure of a TiO2(001) surface for the first time. The nanostructured surface makes the band gap significantly smaller than 3.0 eV only at the surface layer, and the surface state of the crystal enables a visible light response.

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