Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 10, Pages 3430-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8090643
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Funding
- JSPS [20245021]
- Grants-in-Aid for Scientific Research [20245021] Funding Source: KAKEN
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Highly enantio- and diastereosetective direct aldol-type reaction of azlactones with oxocarbenium ions generated by protonation of vinyl ethers using a chiral phosphoric acid catalyst is presented. The method provides efficient access to biologically and pharmaceutically intriguing beta-hydroxy-alpha-amino acid derivatives having a quaternary stereogenic center at the alpha-carbon atom.
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