Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 29, Pages 9886-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja903573p
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Funding
- Scripps Research Institute,
- National Institutes of Health [(NIGMS, I R01 GM084019-02)]
- Sloan Foundation
- National Science Foundation
- Department of Defense, and the Skaggs Oxford Scholarship program
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Pd(0)-catalyzed intermolecular arylation of sp(3) C-H bonds has been achieved using PR3/Arl. This protocol can be used to arylate a variety of aliphatic carboxylic acid derivatives, including a number of bioactive drug molecules. The use of fluorinated aryl iodides also allows for the introduction of fluorine into a molecule of interest.
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