Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 13, Pages 4562-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8088907
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Funding
- MOE in Singapore [ARC12/07, T206B3225]
- NTU [URC, RG53/07, SEP, RG140/06]
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A novel, facile, and highly enantioselective Bronsted acid-catalyzed alpha-hydroxylation of beta-dicarbonyl compounds with up to 99:1 er using nitroso compounds as the oxygen source has been developed. The results disclosed herein considerably extend the substrate scope for the alpha-aminoxylation, allowing expeditious, straightforward, and efficient access to valuable alpha-hydroxy-beta-dicarbonyl compounds with the highest levels of enantiocontrol.
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