Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 36, Pages 12890-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja905153r
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- NNSFC [20771039]
- RGC-CERG [602005, 601706]
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The highly bulky bis-pocket corrole 5,10,15-tris(2,4,6-triphenylphenyl)corrole (H3TTPPC) has been synthesized. Resonance Raman spectroscopy revealed a triply bonded Mn 0 moiety in its manganese(V)-oxo complex. Direct oxygen atom transfer from (TTPPC)Mn O to styrene was confirmed by an O-18-labeling experiment. The (TTPPC)Mn-III complex also exhibits significant shape selectivity in the catalytic epoxidation of nonconjugated dienes.
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