Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 45, Pages 16360-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja907741v
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- NSF [CHE-0910604]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0910604] Funding Source: National Science Foundation
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A stereodynamic, axially chiral triaryl probe is locked into a single conformation upon condensation with two amino alcohol substrates. The welt-defined chiral amplification in the diimines formed results in intense Cotton effects at high wavelengths that can be used for in situ CD analysis of the absolute configuration and of cyclic and acyclic substrates.
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