4.8 Article

A Ring-Opening Metathesis Polymerization Route to Alkaline Anion Exchange Membranes: Development of Hydroxide-Conducting Thin Films from an Ammonium-Functionalized Monomer

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 36, Pages 12888-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja905242r

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Funding

  1. U.S. Department of Energy [DE-FG02-03ER46072]
  2. Sumitomo Corporation
  3. NSERC of Canada

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We report the development of a facile ring-opening olefin metathesis route to alkaline anion exchange membranes via the copolymerization of a tetraalkylammonium-functionalized norbornene with dicyclopentadiene. The thin films generated are mechanically strong and exhibit high hydroxide conductivities and exceptional methanol tolerance.

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