Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 29, Pages 9882-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja903319r
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Funding
- National Institutes of Health [GM58832]
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N-H ketoimines 3a-3v are readily prepared in high yield via organometallic addition to nitrites and isolated as corresponding bench-stable hydrochloride salts. Homogeneous asymmetric hydrogenation of unprotected N-H ketoimines 3a-3v using Ir-(S,S)-f binaphane as catalyst provides chiral amines 4a-4v in 90-95% yield with enantioselectivities up to 95% ee.
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