Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 35, Pages 12516-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja900893p
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Postsynthetic modification of a porous MOF, Zn4O(trans-4,4'-stilbene dicarboxylate)(3),with Br-2 results in bromination of the stilbene units. This is a heterogeneous process, with the stereocontrol originating in the rigidity of the coordinated ligand and the porous nature of the MOF, which allows solution-like access to reactive sites. X-ray diffraction and N-2 sorption studies suggest that partial bromination serves to increase the stability of this interpenetrated MOF structure.
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