4.8 Article

Synthesis and Two-Photon Spectrum of a Bis(Porphyrin)-Substituted Squaraine

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 22, Pages 7510-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja901244e

Keywords

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Funding

  1. National Science Foundation [0524533]
  2. STC program [DMR-0120967]
  3. U.S. Army Research Laboratory [W911NF0420012, 50372-CHMUR]
  4. U.S. Army Research Office [50372-CHMUR]
  5. DARPA [MORPH N00014-06-1-0897]
  6. Directorate For Engineering
  7. Div Of Electrical, Commun & Cyber Sys [0524533] Funding Source: National Science Foundation

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A chromophore in which zinc porphyrin donors are linked through their meso positions by ethynyl bridges to a bis(indolinylidenemethyl) squaraine core has been synthesized using Sonogashira coupling. The chromophore exhibits a two-photon absorption spectrum characterized by a peak cross section of 11000 GM and, more unusually, also exhibits a large cross section of >780 GM over a photon-wavelength window 750 nm in width.

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