4.8 Article

Synthesis of CuInSe2 Nanocrystals with Trigonal Pyramidal Shape

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 9, Pages 3134-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja8080605

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Funding

  1. National Science Foundation [CHE9876674]
  2. Robert A. Welch Foundation
  3. Air Force Research Laboratory [FA8650-07-2-5061]

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The synthesis of monodisperse chalcopyrite (tetragonal) CuInSe2 nanocrystals is reported. The nanocrystals have trigonal pyramidal shape, and they exhibited a common crystallographic orientation when drop-cast onto carbon substrates. A crystallographic model for the nanocrystals was developed. The nanocrystals are bounded by one polar {112} surface facet and three nonpolar {114} surface facets.

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