4.8 Article

Highly Fluorescent Rigid Supramolecular Polymeric Nanowires Constructed Through Multiple Hydrogen Bonds

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 6, Pages 2076-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja8090774

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Funding

  1. Ministry of Science and Technology and National Natural Science Foundation of China [2009CB930604, 2006CB921602, 2007CB808000]

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Suprannolecular polymeric nanowires 1 nconstructed by a 3D shape-persistent hexaacid 1 through multiple hydrogen bonding interactions was developed. Single molecular nanoires were also obtained from its highly dilute solution.Hexaacid 1 containing pi-conjugated chromophores successfully self-assembled to afford these nanofibers with high solid quantum efficiency (22%), which provides us a pathway to fabricate optoelectronic devices using these highly fluorescent nanofibers.

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