Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 5, Pages 1640-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja807302j
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- Deutsche Forschungsgemeinschaft (DFG) [SFB 481]
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Cylindrical polycation brushes form an ionic complex with surfactant sodium dodecyl. sulfate (SDS) in aqueous solution, which causes a worm-to-sphere collapse of the brush. alpha- and beta-Cyclodextrin (CD) returns the brush to the worm-like conformation by forming a supramolecular inclusion complex with SDS. When beta-CD was employed for the inclusion complex, addition of 1-adamantylammonium chloride releases SDS by forming a stronger inclusion complex, causing the recollapse of the brush to spheres.
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