4.8 Article

Isomerization Polymerization of 4-Alkylcyclopentenes Catalyzed by Pd Complexes: Hydrocarbon Polymers with Isotactic-Type Stereochemistry and Liquid-Crystalline Properties

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 31, Pages 10852-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja904150w

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Funding

  1. Ministry of Education, Science, Sports, and Culture, Japan [18750094]
  2. Grants-in-Aid for Scientific Research [18750094] Funding Source: KAKEN

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Isomerization polymerization of 4-alkylcyclopentenes catalyzed by Pd-diimine complexes produces the polymers with trans-1,3-disubstituted cyclopentane rings located regularly along the polymer chain. The polymers with isotactic structure formed by using a C-2-symmetric catalyst exhibited liquid-crystalline properties.

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