4.8 Article

Templating Odd Numbered Magnetic Rings: Oxovanadium Heptagons Sandwiched by β-Cyclodextrins

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 42, Pages 15100-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja9066496

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan

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The oxovanadium heptagons sandwiched by beta-cyclodextrins showed stepped magnetization curves, which were characteristic of level crossings of spin sublevels. Doubly degenerate ground Kramers' doublets split into two spin states, and the splitting energy gaps depend upon ring distortions.

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