4.8 Article

Synthesis of Thermally Stable Extra-Large Pore Crystalline Materials: A Uranyl Germanate with 12-Ring Channels

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 6, Pages 2068-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja8084143

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Funding

  1. National Science Council of Taiwan

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A thermally stable extra-large pore uranyl germanate is synthesized under high-temperature, high-pressure hydrothermal conditions at 585 degrees C and 150 MPa. The structure contains U6+O6 tetragonal bipyramids which are interconnected by digermanate groups to form a 3D framework with 12-ring pore openings.

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