Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 6, Pages 2050-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja8077472
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology of Japan [18550065]
- Japan Interaction in Science and Technology Forum
- SORST program (JST)
- Grants-in-Aid for Scientific Research [18550065] Funding Source: KAKEN
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Low-valent zirconocene species reacted with 1,1,6,6-tetraalkyl-1,2,3,4,5-hexapentaenes to form both 1-zirconacyclopent-3-ynes and n(2)-pi-coordinated complexes according to the alkyl groups (R) and the existence of the neutral ligand (L). Haptotropic interconvertion between these two complexes was observed. It was proposed that double insertion of isocyanide into the Zr-C bond of 1-zirconacyclopent-3-ynes takes place via the isocyanide adduct of the eta(2)-pi-complex as an intermediate.
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