Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 16, Pages 5966-5972Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja900369z
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Funding
- EPSRC
- University of Nottingham
- Engineering and Physical Sciences Research Council [EP/E026974/1] Funding Source: researchfish
- EPSRC [EP/E026974/1] Funding Source: UKRI
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The biomimetic synthesis and structural reassignment of tridachiahydropyrone, tridachiahydropyrone B and tridachiahydropyrone C, isolated from mollusks of the order Sacoglossa, using a sequence of photochemical transformations from a common polyene precursor are described. These complex natural products may act as sunscreens for the producing organism, thus offering protection from harmful UV radiation and oxidative damage.
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