Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 51, Pages 18210-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja907640h
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Funding
- Pioneer Research Program [2008-05103]
- Korean Government (MEST) [R11-2007-050-04002-0]
- Ministry of Education, Science & Technology (MoST), Republic of Korea [N01090032] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
- National Research Foundation of Korea [R11-2007-050-04002-0, 2008-2000097] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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An asymmetric single hollow structure was generated from Ag-Au-Ag heterometal nanorods by a partial galvanic replacement reaction for the first time. The C-2-symmetry breaking took place because of the random generation of a single pit on only one end of the silver domain at an early stage of the reaction. Careful control of the reaction kinetics could also yield a double-hollow structure on both ends of the silver domain. The resulting single- and double-hollow nanorods exhibited characteristic extinctions in the near-IR range.
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