Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 38, Pages 13613-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja904189d
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Funding
- Northwestern Institute for Catalysis in Energy Processes
- DTRA/ARO
- AFOSR
- Northwestern Nanoscale Science and Engineering Center
- NSF/Department of Energy (DOE) [CHE-0535644]
- Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0822838] Funding Source: National Science Foundation
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A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using click chemistry, Using a solvent-based, selective deprotection strategy, two different organic azides were clicked onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.
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