Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 29, Pages 9898-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja903954h
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- French Agence Nationale de la Recherche through the ANR program Heter-eau, [BLAN 06-3_144027]
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Liquid water intrusion in hydrophobic nanoporous silicalite-1, a pure siliceous zeolite, in isothermal conditions under high pressure produces an endothermic effect. After intrusion, confined water in zeolite pores is in a different state from that of the liquid bulk water. Such forced intrusion also chemically modifies the material and tends to render it slightly more hydrophilic.
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