Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 24, Pages 8404-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja902245e
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Funding
- Ministry of Education, Culture, Sports, Science and Technology of Japan [17205008, 18002016]
- Grants-in-Aid for Scientific Research [18002016, 17205008] Funding Source: KAKEN
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The one-electron-reduced form of methylviologen (MV+center dot), generated in situ by bulk electrolysis of methylviologen (MV2+), was for the first time reacted with various Pt(II) complexes in aqueous media without light irradiation to reveal that thermal reduction of water into molecular hydrogen is indeed highly promoted by the Pt(II)-based molecular catalysts.
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