Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 31, Pages 10806-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja904709b
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Funding
- Scripps Research Institute
- U.S. National Science Foundation (NSF) [CHE-0615716]
- Pfizer
- Camille and Henry Dreyfus Foundation
- A. P. Sloan Foundation
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Pd(II)-catalyzed intramolecular amination of arenes is developed using either a one- or two-electron oxidant. The reaction protocol tolerates a wide range of deactivating groups including acetyl, cyano, and nitro groups. This catalytic reaction allows expedient syntheses of broadly useful substituted indolines or indoles.
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