Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 12, Pages 4233-+Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja9001585
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Funding
- Microelectronics Advanced Research Corporation (MARCO)
- Center on Functional Engineered Nano Architectonics (FENA)
- Alfred P. Sloan Fellowship
- Dreyfus Teacher-Scholar Award
- National Science Foundation
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Weakly protected metal nanoparticles (MNPs) are used as precursors for the preparation of catenane- and pseudorotaxane-decorated NPs of various compositions (gold, palladium, platinum). When attached to the surface of MNPs, the molecular switches retain their switching abilities. The redox potentials of these switches depend on and can be regulated by the composition of the mixed self-assembled monotayers covering the MNPs.
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