4.8 Article

Versatile Synthesis of Pentalene Derivatives via the Pd-Catalyzed Homocoupling of Haloenynes

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 8, Pages 2796-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja809930f

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Funding

  1. NSF [CHE0314709]
  2. U.S. DOE [DE-AC02-05CH11231]

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A palladium-catalyzed, reductive homocoupling of haloenynes yields a diverse range of polysubstituted pentalene derivatives, including annulated dibenzopentalenes and dithienylpentalenes.

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