4.8 Article

A Pd(II)-Catalyzed Ring-Expansion Reaction of Cyclic 2-Azidoalcohol Derivatives: Synthesis of Azaheterocycles

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 131, Issue 36, Pages 12886-+

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja9049564

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Funding

  1. Nanyang Technological University, Singapore Ministry of Education, and Science & Engineering Research Council (A*STAR) [082 101 0019]

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A Pd(II)-catalyzed ring expansion-reaction of cyclic 2-azidoalcohol derivatives was found to proceed via an unprecedented C-C bond cleavage-C-N bond formation sequence, providing substituted azaheterocycles.

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